)Tj Q h EMC /TT0 1 Tf )Tj (Personal Protective Equipment)Tj 7.688 738 m 8.457 456.479 m f 122.666 106.521 l 11.533 326.023 l 485.294 443.793 117.479 11.917 re Q 0 -1.2 TD 484.526 456.479 m q 363.873 107.29 238.901 11.917 re 0000060195 00000 n ET ( 3.4 )Tj /TT1 1 Tf ( )Tj /TT0 1 Tf /Artifact <>BDC (compounds- water soluble\). )Tj /TT1 1 Tf f Q 484.526 443.024 m May cause severe and permanent damage to the dige\ stive tract. f 157.997 542.588 l 9.226 93.836 l f h 0000000472 00000 n 306 617.55 l 122.666 66.157 l )Tj h f )Tj 0.313 0.313 0.313 rg 602.774 141.56 l q /Artifact <>BDC (Section 5 - Fire Fighting Measures )Tj 604.312 113.881 l f /TT0 1 Tf 10.764 248.801 l 0 -1.201 TD 601.236 679.395 l 604.312 709.878 m (is subject to the reporting requirements of Section 313 of SARA Title II\ I and 40 CFR Part 373. 602.774 133.047 l W* n 601.236 703.255 l 602.774 517.218 l 0.457 0.449 0.431 rg 604.312 428.8 l EMC 0 18 612 756 re EMC 0.313 0.313 0.313 rg 0 Tc 0 Tw 0 Ts 100 Tz 0 Tr 6.9196 0 0 6.9196 18 781.7488 Tm 363.104 93.067 m 604.312 676.32 l >> The CLP Regulation makes sure that the hazards presented by chemicals are … 602.774 430.338 l EMC h (Eyes:)Tj h 122.666 79.612 l )Tj f /TT1 1 Tf 363.104 119.976 l W* n EMC EMC 122.666 119.976 m Use a )Tj 604.312 680.662 l 0.457 0.449 0.431 rg EMC (Hazardous Decomposition Products:)Tj /TT0 1 Tf 8.457 443.024 m EMC 0 -1.201 TD h h q An increase in incidence of lung cancer has been Q 604.312 322.179 l ( Oral, mouse: LD50 = 127 mg/kg; )Tj (Catalog Numbers:)Tj h (0.05 mg/m3 TWA \(as Cr\) \(listed )Tj 0 -1.201 TD q ( )Tj 0.801 0.801 0.801 rg T* 9.226 497.206 l 0 18 612 756 re 0000066407 00000 n (state of California to cause cancer. 10.764 134.584 l ( R 35 Causes severe burns. 604.312 541.05 l (Section 16 - Additional Information )Tj 9.226 542.588 l h /T1_0 1 Tf /Artifact <>BDC h (Chemical waste generators must determine whether a discarded chemical is\ classified as a hazardous waste. )Tj endstream endobj 35 0 obj<> endobj 36 0 obj<> endobj 37 0 obj<>stream f 5.3819 0 0 5.3819 27.4577 500.6129 Tm 9.226 618.319 l -42.948 -1.555 Td 454.003 618.319 l (California Prop 65)Tj (MSDS contains all of the information required by those regulations. 70197 Causes chemical burns to the respiratory tract. 0 18 612 756 re )Tj /TT0 1 Tf 377.41 443.024 m (Neurotoxicity:)Tj 122.666 93.067 l 376.641 430.338 l T* f ( )Tj 602.774 677.857 l (absorb material, then place into a suitable clean, dry, closed container\ for disposal. Q W* n W* n 122.666 52.702 l 0 -1.201 TD f ( Fish: Pseudomonas putida: )Tj h 10.715 0 Td 10.7638 0 0 10.7638 7.6884 236.8076 Tm ( R 48/23 Toxic : danger of serious damage to health by prolonged )Tj /T1_0 1 Tf (Containers may explode in the heat of a fire. 1 0 obj<> endobj 2 0 obj<> endobj 3 0 obj<> endobj 5 0 obj<> endobj 7 0 obj<> endobj 8 0 obj<>>> endobj 9 0 obj<> endobj 10 0 obj<><><><><>]/P 9 0 R/S/Article/T()/Pg 11 0 R>> endobj 11 0 obj<>/ProcSet[/PDF/Text]>>/Type/Page>> endobj 12 0 obj<> endobj 13 0 obj[10 0 R] endobj 14 0 obj<>/ProcSet[/PDF/Text]>>/Type/Page>> endobj 15 0 obj[10 0 R] endobj 16 0 obj<>/ProcSet[/PDF/Text]>>/Type/Page>> endobj 17 0 obj[10 0 R] endobj 18 0 obj<>/ProcSet[/PDF/Text]>>/Type/Page>> endobj 19 0 obj[10 0 R] endobj 20 0 obj<>/ProcSet[/PDF/Text]>>/Type/Page>> endobj 21 0 obj[10 0 R] endobj 22 0 obj<>/ProcSet[/PDF/Text]>>/Type/Page>> endobj 23 0 obj[10 0 R] endobj 24 0 obj<> endobj 25 0 obj<> endobj 26 0 obj<> endobj 27 0 obj<> endobj 28 0 obj<> endobj 29 0 obj<>stream f 602.774 680.166 l (Spills/Leaks:)Tj f May cause allergic re\ spiratory and skin reaction. 0 18 612 756 re ( Chromium\(VI\) oxide )Tj 604.312 541.05 l /TT1 1 Tf 121.524 443.024 m ( )Tj h 0 -1.201 TD 0 -1.2 TD ( None of the chemicals in this product are considered highly hazardo\ us by OSHA. (Section 313)Tj /Artifact <>BDC T* 0 18 612 756 re f 601.236 134.584 l 454.003 542.588 l 484.526 456.479 m (rposes. 0 0 0 rg ( )Tj 485.294 443.793 l /TT0 1 Tf T* /TT1 1 Tf q 362.335 93.836 l h 121.897 78.843 l Use water )Tj 603.543 541.819 l f The related chromium(III) derivatives are not particularly dangerous; thus, reductants are used to destroy chromium(VI) samples. (Section 4 - First Aid Measures )Tj 363.104 93.067 m f 11.533 135.353 l h ET First Aid Measures First-aid measures 602.774 138.009 l 0 -1.201 TD /T1_0 1 Tf 8.457 66.157 m 10.764 388.052 m 0 -1.201 TD f /TT0 1 Tf 0 0 0 rg /TT0 1 Tf (Chemical Name)Tj (OSHA - Final PELs)Tj /TT1 1 Tf ( )Tj 0000027362 00000 n h 8.457 93.067 m uuid:1b58ec6f-7f68-47d2-aec3-496b1cf28cdb 156.46 616.781 l 601.236 702.46 m 7.688 113.881 l 10.764 252.252 m (metals, diethyl formamide, phosphorus, hydrocarbons, ketones. Q ( )Tj EMC f /TT1 1 Tf h 157.997 618.319 147.234 11.917 re /TT1 1 Tf (https://fscimage.fishersci.com/msds/95984.htm)Tj f 600.467 383.787 l EMC May cause cyanosis \(bluish discoloration of skin due to \ deficient oxygenation of the blood\). 454.771 631.005 m 9.226 164.15 l W* n -3.095 -2.571 Td EMC EC-No. 9.226 442.255 l 11.533 156.881 l 0 0 0 rg 121.897 105.753 l 602.774 708.341 l (MSDS Creation Date:)Tj 0.313 0.313 0.313 rg 0 0 0 rg 600.467 704.023 l 120.755 442.255 l 10.7638 0 0 10.7638 7.6884 104.9636 Tm 10.764 678.628 m 602.774 491.077 l 603.543 541.819 l (The following statement\(s\) is\(are\) made in order to comply with the \ California Safe Drinking Water Act:)Tj 455.54 542.588 l 0.753 0.753 0.753 rg f q 0 18 612 756 re f 362.335 92.298 l 121.524 443.024 l )Tj /TT1 1 Tf f /TT1 1 Tf 0 18 612 756 re 7.688 245.725 l f f (European Labeling in Accordance with EC Directives)Tj (General Information:)Tj q q /T1_0 1 Tf 601.236 411.117 m 454.771 541.819 l 120.755 443.793 l T* 604.312 498.743 m Exposure to chromium 6 compounds can increase the risk of lung cancer. h (This product has been classified in accordance with the hazard criteria \ of the Controlled Products Regulations and the )Tj /TT1 1 Tf 602.774 407.621 l )Tj 10.764 411.117 m 21.929 -0.001 Td 9.226 542.588 l (Ingestion:)Tj Q (Risk Phrases:)Tj 604.312 518.756 m 0 -1.201 TD q (Storage of Liquid and Solid Oxidizers. 9.226 115.419 l ( CAS# 1333-82-0: Section 6, 0.1 % de minimus concentration [see 40 C\ FR 749.68] )Tj 0 -1.2 TD h 9.226 703.998 l ( )Tj 0 -1.2 TD 600.467 656.331 l 604.312 705.536 l f /TT0 1 Tf 7.688 489.539 m ( 201-796-7100 )Tj 8.457 541.819 l 7.688 384.976 l (Eye:)Tj 602.774 349.857 l h (Section 12 - Ecological Information )Tj 13.4548 0 0 13.4548 181.9201 255.9136 Tm 0 -1.2 TD Specific hazards arising from the chemical Emits toxic fumes (chromium oxides) under fire conditions. /TT0 1 Tf Q Remove from exposure and move to fresh air\ immediately. 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Q 9.226 386.514 593.548 26.141 re 604.312 631.774 m /TT0 1 Tf (which becomes evident upon re-exposure to this material. /TT1 1 Tf )Tj 7.688 652.487 m 454.771 541.819 l 7.688 160.725 m 13.4548 0 0 13.4548 177.1302 686.5076 Tm (Section 2 - Composition, Information on Ingredients )Tj (Section 6 - Accidental Release Measures )Tj f f 602.774 92.298 l Strong oxidiz\ er. 363.104 119.976 m h 0.313 0.313 0.313 rg /TT1 1 Tf h f ( )Tj (Engineering Controls:)Tj f 0.801 0.801 0.801 rg f 0 -1.201 TD 7.688 467.183 l 0 18 612 756 re ( As in any fire, wear a self-contained breathing apparatus in pressure-d\ emand, MSHA/NIOSH )Tj 11.533 271.097 l endstream endobj 38 0 obj(https://fscimage.fishersci.com/msds/95984.htm) endobj 39 0 obj<> endobj 40 0 obj<> endobj 41 0 obj<> endobj 42 0 obj<> endobj 43 0 obj[40 0 R] endobj 44 0 obj(https://fscimage.fishersci.com/msds/95984.htm) endobj 45 0 obj(üöû�sêÁ­a€FÌzÚ) endobj 46 0 obj<> endobj 47 0 obj<> endobj 48 0 obj(ìØÕpXnC—!ítÂ) endobj 49 0 obj<> endobj 50 0 obj<> endobj 51 0 obj<> endobj 52 0 obj<> endobj 53 0 obj<> endobj 54 0 obj<>stream 603.543 631.005 l q q 9.226 53.471 l 122.292 442.255 l 9.226 677.857 l 363.873 92.298 l ET /WebCaptureBG BMC /TT0 1 Tf f 603.543 456.479 m 0 18 612 756 re /TT1 1 Tf 7.688 165.687 m /TT0 1 Tf 600.467 725.551 l 0.753 0.753 0.753 rg /TT0 1 Tf ( T+ O N )Tj )Tj T* Cancer )Tj 7.688 469.527 l /TT0 1 Tf BT (LD50/LC50:)Tj 7.688 631.774 m 604.312 51.934 l 0 0 0 rg "R}~Q:~pgg'������"���l���/���������O�:OϽV�ޞ�~ @����������zo��“7��g;)�Kߜӗ���;�����=�d�������'}z��8}����7w�7?���I�������u��w?ݾw��~�����i�����k���K�^��^'��d4k����˗;�g����_�u_�������L��OC6���($uiz["��Dڻw�#������r{ogw烺��������W! h f 600.467 139.253 l 603.543 66.157 l 8.457 106.521 m (protection regulations in 29 CFR 1910.133 or European Standard EN166. ( R 46 May cause heritable genetic damage. 363.104 66.157 l (Epidemiology:)Tj f h EMC 601.236 706.803 m f (collect in low or confined areas. )Tj ET 10.764 741.075 l 10.764 726.32 m 10.764 411.117 m 363.104 52.702 l (5 \346g/m3 TWA \(listed under )Tj h h 10.764 470.259 m W* n 0.949 0.945 0.935 rg f ( This material does not contain any hazardous air pollutants. 0.753 0.753 0.753 rg (A100-100, A100-212, A100-500, A98-212, A98-500, NC9210244, S79969ACS, XX\ A100100LB )Tj 0000066279 00000 n The ‘Hazard classification and labelling’ section shows the hazards of a substance through a standardised system of statements and pictograms, as has been established under CLP (Classification Labelling and Packaging) Regulation. h 602.774 443.793 l 121.524 429.569 l 600.467 271.097 l h W* n /T1_0 1 Tf 604.312 680.662 l 0 -1.2 TD 602.774 107.29 l 604.312 681.703 l 0 -1.201 TD /TT1 1 Tf 0000002339 00000 n 600.467 492.555 l 601.236 495.668 l T* 0 0 0 rg 0 18 612 756 re 601.236 325.254 l 600.467 677.859 l (other symptoms are experienced. 8.457 66.157 m 0 0 0 rg Use only in a well-)Tj Substance\ is readily absorbed through the skin. May impair fertility. (Decomposition Temperature:)Tj 305.231 630.236 l f (During a fire, irritating and highly toxic gases may be generated by the\ rmal decomposition or combustion. 0 -1.199 TD /Article <>BDC 601.236 492.615 l 9.226 227.648 l 11.533 410.348 l ( dark red to purple )Tj 8.457 429.569 l /Artifact <>BDC 0000066576 00000 n Get medical aid immediately.\ )Tj Q f 0.929 -1.2 Td (RCRA U-Series:)Tj f See also Stability and Reactivity section. 10.764 157.65 m 8.457 541.819 l 455.54 618.319 l EMC /TT0 1 Tf 0 -1.2 TD ( None of the chemicals in this product are listed as Priority Pollut\ ants under the CWA. h EMC Hexavalent chromium [Cr (VI)] is one of the valence states (+6) of the element chromium. W* n (2.7 \(Water=1\) )Tj Q 7.688 681.703 m 13.4548 0 0 13.4548 135.2253 710.3673 Tm 10.764 388.052 l Keep container )Tj f 0 -1.201 TD /TT0 1 Tf 9.226 247.263 l h /T1_0 1 Tf (associated with lung cancer and gastrointestinal tract tumors. T* endobj h h (Section 12b)Tj f 483.757 430.338 l (General Information:)Tj 0.949 0.945 0.935 rg T* (WARNING: This product contains Chromium trioxide, listed as `Chromium \(\ VI\) compounds', a chemical known to the )Tj 122.666 93.067 l (Section 10 - Stability and Reactivity )Tj 604.312 467.183 l EMC /TT0 1 Tf /Artifact <>BDC 5.3819 0 0 5.3819 27.4577 512.5428 Tm 0 -1.2 TD ( None of the chemicals in this product are listed as Toxic Pollutant\ s under the CWA. f 362.335 105.753 l 9.9358 0 0 9.9358 7.6884 420.5685 Tm W* n (California No Significant Risk Level: None of the chemicals in this prod\ uct are listed. EMC EMC f /TT1 1 Tf ET 0.753 0.753 0.753 rg 602.774 455.71 l ( )Tj f 7.688 255.327 m 0 -1.201 TD /TT1 1 Tf h 0 Tc 0 Tw 0 Ts 100 Tz 0 Tr 6.9196 0 0 6.9196 18 781.7488 Tm 10.764 706.803 m 122.666 79.612 m 7.688 136.471 m -20.594 -1.202 Td 156.46 618.319 l /TT1 1 Tf Hazards not otherwise classified (HNOC) Other hazards Very toxic to aquatic life with long lasting effects Harmful to aquatic life Section 3. 0.753 0.753 0.753 rg /TT1 1 Tf 8.457 429.569 l h uuid:e963d2fd-ef89-45c1-bd16-f68d10cb2dce h h W* n (Chronic ingestion may cause effects similar to those of acute ingestion.\ May cause liver and kidney damage. 123.434 93.836 l This compound is a dark-purple solid under anhydrous conditions, bright orange when wet and which dissolves in water concomitant with hydrolysis. Death has been avoided in several cases through the use of early renal dialys is. 0000000663 00000 n 11.437 0 Td ET 604.312 705.536 m 602.774 386.514 l T* h 9.226 65.388 l 485.294 430.338 l h W* n T* (European/International Regulations)Tj (https://fscimage.fishersci.com/msds/95984.htm \(4 of 6\)7/23/2007 11:01:\ 40 AM)Tj h feet, dizziness, lightheadedness, chest pain, muscle pain … 0 -1.2 TD (CAS# 1333-82-0: )Tj 8.457 456.479 m Cr (VI) is known to cause cancer. 0 -1.201 TD Q 11.533 347.551 l ( )Tj /Artifact <>BDC f 0 18 612 756 re 0 -1.201 TD )Tj 602.774 323.717 l (EINECS/ELINCS)Tj 9.226 471.065 l 363.873 65.388 l 0.801 0.801 0.801 rg 601.236 134.584 l 9.226 680.166 l 120.755 443.793 l 0 -1.201 TD 13.4548 0 0 13.4548 187.5038 141.697 Tm 0.753 0.753 0.753 rg /TT0 1 Tf 363.873 93.836 l Provide ventilation. 0 -1.2 TD Q W* n 601.236 383.018 l q f f 122.666 106.521 m 11.533 135.353 l 363.104 119.976 m h 600.467 494.899 l (pyridine, dimethyl formamide, acetic acid, acetic anhydride, acetone, di\ ethyl ether, ethanol, methanol, camphor, )Tj Identification . 123.434 53.471 l 8.457 119.976 l If breathing is difficult, give oxygen. 602.774 618.319 l 122.666 79.612 m 11.533 725.551 l 6.9196 0 0 6.9196 18 8.7488 Tm )Tj 601.236 726.32 l (Emergency Number:)Tj ( Do not store near combustible materials. EMC 0.801 0.801 0.801 rg EMC 27.798 0 Td 602.774 703.998 l 0 Tc 0 Tw 0 Ts 100 Tz 0 Tr 6.9196 0 0 6.9196 18 781.7488 Tm q ( R 24/25 Toxic in contact with skin and if swallowed. 604.312 143.097 m 601.236 248.801 l h 603.543 79.612 l 7.688 120.745 m 600.467 135.353 l h 0 -1.199 TD 10.7638 0 0 10.7638 7.6884 313.2612 Tm %PDF-1.4 484.526 429.569 l q )Tj f (EMERGENCY OVERVIEW)Tj 7.688 541.05 l 363.873 53.471 l f 0000000406 00000 n 306 631.005 m 363.104 93.067 m (Molecular Formula:)Tj 363.104 66.157 l 0 0 0 rg 604.312 131.509 l (Inhalation:)Tj 0 -1.2 TD 10.764 116.957 l h 9.9358 0 0 9.9358 7.6884 458.9516 Tm q 9.226 517.218 l 122.292 455.71 l h (UN1463)Tj f h /TT0 1 Tf Cont\ act professional fire-)Tj 123.434 107.29 238.901 11.917 re )Tj 362.335 119.207 l Can react violently upon contact with reducing reagents, including organic matter, leading to ignition or explosion. 0000003639 00000 n 0 Tc 0 Tw 0 Ts 100 Tz 0 Tr 6.9196 0 0 6.9196 18 781.7488 Tm ( )Tj 377.41 443.024 l ( )Tj 602.774 471.065 l 0 -1.1 TD 0.753 0.753 0.753 rg 11.533 514.911 l ( Not available. EMC 6.9196 0 0 6.9196 18 8.7488 Tm 9.394 0 Td 306 631.005 m Q 0.753 0.753 0.753 rg h 378.179 442.255 l (ignite organic matter on contact., bases, alcohols, alkali metals, ammon\ ia, chlorine trifluoride, finely powdered )Tj 13.4548 0 0 13.4548 192.6234 395.1644 Tm f )Tj f 9.226 618.319 l 7.688 676.32 m Chromium (VI) is much more toxic than chromium (III), for both acute and chronic exposures. f 0 -1.2 TD f 10.764 655.563 l 0 -1.201 TD 603.543 617.55 l )Tj 121.897 65.388 l 604.312 245.725 l 603.543 631.005 m 121.524 456.479 m h 601.236 493.324 l 0000066330 00000 n (Storage:)Tj /TT1 1 Tf h 9.226 494.862 l (Inhalation:)Tj 122.292 455.71 l /TT0 1 Tf Do NOT allow victim to rub eyes or keep ey\ es closed. f Causes redn\ ess and pain. (NIOSH/MSHA or European Standard EN 149 approved respirator if exposure l\ imits are exceeded or if irritation or )Tj f (wheezing, shortness of breath and pulmonary edema. Q 0 18 612 756 re 601.236 683.738 l /TT1 1 Tf f 378.179 443.793 l EMC q 8.457 631.005 m f h 0 18 612 756 re h ( )Tj )Tj 0 -1.201 TD ( s waste. 0 18 612 756 re /Artifact <>BDC 602.774 78.843 l h (dusts, vapors, or mists may result in the perforation of the nasal septu\ m. May cause systemic effects. (\(approved or equivalent\), and full protective gear. 7.688 51.934 m 10.764 134.584 m EMC 123.434 80.381 l T* 363.104 66.157 m 601.236 348.32 m 602.774 494.862 l reaction may include rash, itching, swelling, trouble breathing, tingling of the hands and. EMC 602.774 66.926 l h ( )Tj W* n 604.312 496.4 m h 600.467 156.881 l h Q )Tj sol.\) )Tj 0 -1.199 TD 306.769 616.781 l Chromic acid (CrO 3 ), Chromic anhydride, Chromic oxide, Chromium(VI) oxide (1:3), Chromium trioxide, Zinc chromate CrO 3 : Dark-red, odorless flakes or powder. 122.666 79.612 m 0 18 612 756 re Chromium Trioxide is a highly insoluble thermally stable Chromium source suitable for glass, optic and ceramic applications. 17.152 0 Td )Tj ( )Tj 9.226 349.857 l 376.641 455.71 l Users should make their own investigations to determine th\ e suitability of the information for their particular pu)Tj 156.46 630.236 l 0.457 0.449 0.431 rg 0.313 0.313 0.313 rg h 0000000229 00000 n 10.7638 0 0 10.7638 7.6884 122.5911 Tm 0 -1.2 TD https://fscimage.fishersci.com/msds/95984.htm Q 0.949 0.945 0.935 rg h h 600.467 680.164 l 121.897 53.471 l 363.104 66.157 l h W* n /TT1 1 Tf /TT1 1 Tf (removing contaminated clothing and shoes. 483.757 455.71 l endstream endobj 32 0 obj<> endobj 33 0 obj<>stream /T1_0 1 Tf f 0.753 0.753 0.753 rg (oxygen.. )Tj h h 363.873 53.471 l 485.294 442.255 l 9.9358 0 0 9.9358 7.6884 303.1834 Tm h h Q 0.753 0.753 0.753 rg h /Artifact <>BDC 603.543 429.569 l Q If victim is conscious and alert, give 2-4 cupf\ uls of milk or water. 7.688 428.8 l 454.771 631.005 m 0 18 612 756 re 0 -1.2 TD 604.312 469.527 l 602.774 412.655 l ( R 22 Harmful if swallowed. 0 -1.201 TD Discard contaminated shoes. 9.226 517.218 l (Chemical Stability:)Tj /TT1 1 Tf 602.774 766.312 l 602.774 407.621 l h f /WebCaptureBG BMC (Teratogenicity:)Tj (5.1)Tj f /Artifact <>BDC 601.236 388.052 l /Artifact <>BDC 603.543 93.067 l -51.259 -5.156 Td 0 18 612 756 re )Tj W* n /Artifact <>BDC f f ( )Tj f /TT0 1 Tf 603.543 66.157 l 0 -1.201 TD T* 0 18 612 756 re 600.467 161.843 l ( 250 deg C \( 482.00 deg F\) )Tj 0.457 0.449 0.431 rg 11.5327 0 0 11.5327 246.7509 740.5341 Tm /Artifact <>BDC 604.312 384.976 l 0.801 0.801 0.801 rg 10.764 271.866 m /T1_0 1 Tf 122.666 93.067 m 0 18 612 756 re (Chemical Test Rules)Tj 121.524 443.024 m q Q f W* n h 0 18 612 756 re /TT1 1 Tf /Artifact <>BDC 483.757 442.255 l 363.104 66.157 m q )Tj Immediately flush skin with plenty of wate\ r for at least 15 minutes while )Tj h ( )Tj (ity resulting )Tj (membranes. 7.688 322.179 l 0 0 0 rg 377.41 456.479 m f h /Artifact <>BDC 157.229 617.55 l 602.774 80.381 l 454.003 630.236 l /WebCaptureFN <>BDC ( Wear a chemical apron. (Physical State:)Tj Product form : Substance /TT1 1 Tf 9.9358 0 0 9.9358 7.6884 94.8857 Tm 10.764 348.32 m f q 9.226 654.025 593.548 26.141 re h f (RTECS#:)Tj 123.434 93.836 l 122.666 52.702 m Substance is … /WebCaptureFN <>BDC (Prolonged or repeated skin contact may cause sensitization dermatitis an\ d possible destruction and/or ulceration. f 0.457 0.449 0.431 rg 7.688 131.509 l 7.688 51.934 l 0 -1.2 TD f 7.688 680.662 l /Artifact <>BDC 9.226 739.538 593.548 26.774 re 0 -1.201 TD Contact with other material may )Tj 600.467 701.691 l q /TT0 1 Tf h 7.688 409.158 m 602.774 164.15 l 0 0 0 rg [Note: Often used in an aqueous solution (H 2 CrO 4 ).] (For CHEMTREC assistance, call:)Tj ( <1.0 \(50g/l aq. 11.533 701.691 l (Evaporation Rate:)Tj f Chronic exposure to water insoluble hexavalent chromiu\ m compounds has been shown to be )Tj (CHROMIUM TRIOXIDE, ANHYDROUS)Tj f 9.226 407.621 l 0.457 0.449 0.431 rg EMC 0000005309 00000 n /TT0 1 Tf h Q 0000065802 00000 n ( )Tj /TT0 1 Tf h 0 0 0 rg 7.688 709.878 m ( R 9 Explosive when mixed with combustible material. 601.236 252.252 m /Artifact <>BDC 11.533 684.507 l h f h ( Get medical aid immediately. f Use adequate general or local exhaust ventilation to keep\ airborne concentrations below the )Tj /TT0 1 Tf 121.524 456.479 m 0 -1.2 TD h BT ( Stable under normal temperatures and pressures. 0.801 0.801 0.801 rg 602.774 247.263 l W* n 600.467 326.023 l 601.236 348.32 l 306 541.819 l 8.457 429.569 m (SARA Codes)Tj 0 -1.199 TD EMC (II)Tj f 600.467 684.507 l h /TT0 1 Tf ( 1333-82-0: GB6650000 )Tj 122.666 93.067 m It is also attacked by concentrated alkali to yield salts of [Cr(OH) 6] 3−. 0000000000 00001 f Q 0 -1.2 TD q f ( None of the chemicals in this product are under a Chemical Test Rul\ e. )Tj /T1_1 1 Tf /TT0 1 Tf 0 i 0.313 0.313 0.313 rg See also NFPA 430, Code for the )Tj 0.457 0.449 0.431 rg f 122.292 443.793 l 0000065766 00000 n T* 604.312 457.248 l 602.774 253.789 l 485.294 443.793 l 121.897 53.471 l 601.236 493.324 m ( Wear a chemical apron. (For information, call:)Tj )Tj /TT0 1 Tf 378.179 442.255 l 7.688 469.527 m 0 -1.201 TD T* 455.54 630.236 l 0 -1.1 TD 0 18 612 756 re /TT1 1 Tf W* n 0 -1.1 TD f 0 18 612 756 re ( )Tj /TT1 1 Tf 11.533 656.331 l feet, dizziness, lightheadedness, chest pain, muscle pain or flushing. )Tj 9.226 115.419 l 6.9196 0 0 6.9196 18 8.7488 Tm T* 0 -1.2 TD f 363.873 119.207 l 11.533 493.384 l h /TT0 1 Tf 7.688 160.725 m 123.434 92.298 l 602.774 442.255 l 0 -1.201 TD 123.434 107.29 l f 11.533 493.384 l 604.312 379.942 l )Tj /WebCaptureFN <>BDC 454.003 618.319 l /TT1 1 Tf 18.528 0 Td h f May cause skin\ sensitization, an allergic reaction, )Tj ( CAS# 1333-82-0 is listed on the TSCA inventory. 10.764 229.186 m 377.41 456.479 m 122.666 93.067 m (US FEDERAL)Tj q ( )Tj W* n 602.774 253.789 l 0 -1.2 TD ( )Tj 376.641 430.338 l ET 362.335 66.926 l /TT0 1 Tf 0 18 612 756 re 0.313 0.313 0.313 rg 7.688 518.756 m 121.524 443.024 m (guidelines for the classification determination are listed in 40 CFR Par\ ts 261.3. f /Artifact <>BDC 602.774 497.206 l f 0.313 0.313 0.313 rg 363.104 52.702 m /Artifact <>BDC h 13.4548 0 0 13.4548 190.3024 479.7154 Tm 0 -1.2 TD /TT0 1 Tf f f h OSHA Vacated PELs: Chromium trioxide: No OSHA Vacated PELs are listed for this chemical. h h 9.9358 0 0 9.9358 76.7038 717.9627 Tm 26.509 0 Td 10.764 162.612 m 123.434 78.843 l 363.104 79.612 l T* (Clean Air Act:)Tj 7.688 518.756 m /TT0 1 Tf 306.769 618.319 147.234 11.917 re ET Store in a cool, dry, well-)Tj 7.688 700.179 l May cause irreversible eye injury. h (Hazard Class:)Tj W* n 10.764 470.259 l 0000066012 00000 n ( )Tj 10.764 406.083 m )Tj 27.798 0 Td 9.226 491.077 l 23.498 -0.001 Td f EMC f 0 -1.2 TD h 13.4548 0 0 13.4548 184.2679 146.6595 Tm /Producer(Sub Systems, Inc.)/CreationDate(D:20180118163219+05'00')/ModDate(D:20180118163219+05'00')/Creator(Sub Systems, Inc.) -50.569 -1.555 Td 305.231 542.588 l )Tj ( S 53 Avoid exposure - obtain special instructions before use. EMC 7.688 498.743 m 10.764 139.547 l 601.236 678.628 l f T* stream ( S 60 This material and its container must be disposed of as hazardo\ u )Tj Index-No. 484.526 429.569 l 10.7638 0 0 10.7638 365.2491 740.5341 Tm 601.236 470.259 l )Tj 9.9358 0 0 9.9358 38.4422 476.7533 Tm q 7.688 245.725 m (https://fscimage.fishersci.com/msds/95984.htm \(6 of 6\)7/23/2007 11:01:\ 40 AM)Tj ( )Tj 600.467 326.023 l /TT1 1 Tf 604.312 631.774 l ( )Tj h /TT2 1 Tf 13.4548 0 0 13.4548 128.471 477.3716 Tm 604.312 652.487 l May cause allergic skin reaction. 0.313 0.313 0.313 rg (Material Safety Data Sheet )Tj )Tj W* n 483.757 443.793 l )Tj (ventilated area. 7.688 680.662 m )Tj (MSDS Name:)Tj 14. /Artifact <>BDC 306.769 630.236 l 0 18 612 756 re T* f 7.688 322.179 m )Tj However, certain perovskite structured oxides are electronically conductive finding application in the cathode of solid oxide fuel cells and oxygen generation systems. EMC h 156.46 616.781 l 9.226 630.236 l EMC Proper Shipping Name: Chromium trioxide, anhydrous UN#: 1463 Class: 5.1 Packing Group: Packing Group II Hazard Label: Oxidizer Hazard Label: Corrosive PIH: Not PIH IATA Proper Shipping Name: Chromium trioxide, anhydrous IATA UN Number: 1463 Hazard Class: 5.1 Packing Group: II Section 15 - Regulatory Information EU DIRECTIVES CLASSIFICATION 121.897 92.298 l 7.688 136.471 l f 602.774 491.077 l 0 -1.2 TD ( )Tj (Molecular Weight:)Tj 604.312 160.725 l ( Fisher Scientific )Tj BT 0 -1.201 TD /TT0 1 Tf Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. 602.774 701.717 l 0 i EMC f 602.774 468.721 l h /TT0 1 Tf 306 617.55 m /Article <>BDC (adequate ventilation. 7.688 379.942 m 0.457 0.449 0.431 rg ET Q /TT0 1 Tf W* n 363.104 79.612 l ( )Tj Q 122.292 443.793 l (Notes to Physician:)Tj /TT1 1 Tf /TT0 1 Tf 377.41 443.024 l 157.997 630.236 l 0 -1.201 TD /WebCaptureFN <>BDC /TT1 1 Tf 10.764 248.801 m 602.774 430.338 l /TT0 1 Tf 0 18 612 756 re 0.313 0.313 0.313 rg q ( )Tj f 0 -1.2 TD 8.457 106.521 m /TT0 1 Tf 306.769 630.236 l 0 18 612 756 re /TT0 1 Tf X���`I�%&/m�{J�J��t��`$ؐ@������iG#)�*��eVe]f@�흼��{���{���;�N'���?\fdl��J�ɞ!���?~|? ( )Tj 0.753 0.753 0.753 rg EMC 603.543 617.55 l h f Wear appropriate protective gloves to prevent sk\ in exposure. (482 deg F )Tj /Artifact <>BDC h /TT0 1 Tf 377.41 443.024 m 604.312 379.942 l 603.543 66.157 m 123.434 53.471 l 602.774 494.862 l 602.774 66.926 l f ( )Tj h 10.764 492.615 l (l)Tj (NFPA Rating:)Tj /Artifact <>BDC /TT0 1 Tf )Tj (Appearance:)Tj f (TDLO/TCLO-LOWEST PUBLISHED TOXIC DOSE/CONC. q 306 617.55 l 604.312 136.471 l /Artifact <>BDC 602.774 105.753 l q 0.753 0.753 0.753 rg )Tj 0 18 612 756 re )Tj 363.873 80.381 l 0 -1.201 TD EMC 306.769 616.781 l EMC f /Artifact <>BDC 601.236 325.254 l 600.467 677.859 l 601.236 702.46 l 9.9358 0 0 9.9358 7.6884 758.6238 Tm 0 -1.201 TD 9.226 739.538 l EMC 0 -1.201 TD 10.764 406.083 m 11.533 229.955 l 122.666 52.702 l ( Facilities storing or utilizing this material should be equipped with a\ n eyewash facility and a )Tj Strong oxidizer. EMC \ )Tj h 603.543 119.976 l f 604.312 738 l 122.666 66.157 l ( Solid )Tj 363.873 78.843 l 9.226 273.404 l 0 -1.201 TD f (1910.1026\) \(listed under )Tj /TT0 1 Tf Q /TT0 1 Tf In no )Tj 363.873 92.298 l 0 -1.199 TD f f h BT q 0 -1.201 TD T* 9.226 442.255 l 600.467 229.955 l EMC 0 -1.201 TD 0000000880 00000 n (Packing Group:)Tj 10.764 229.186 l f 9.226 80.381 l (Flash Point:)Tj h 0000065703 00000 n 122.292 442.255 l )Tj (215-607-8)Tj 122.666 106.521 l 0 -1.1 TD 454.771 617.55 l (Explosion Limits, Lower:)Tj T* May cause )Tj q /TT0 1 Tf /Artifact <>BDC /WebCaptureBG BMC 601.236 472.603 l 9.226 247.263 593.548 26.141 re 9.9358 0 0 9.9358 7.6884 360.9467 Tm h 0 -1.199 TD 0 18 612 756 re /TT1 1 Tf 9.226 133.047 593.548 26.141 re Q 362.335 80.381 l 10.7638 0 0 10.7638 7.6884 691.2613 Tm /TT1 1 Tf 7.688 467.183 m 602.774 119.207 l /TT0 1 Tf ( R 42/43 May cause sensitization by inhalation and skin contact. /Artifact <>BDC T* (>98 )Tj T* 122.292 443.793 254.349 11.917 re Causes burns by all exposure routes. (Specific Gravity/Density:)Tj f 0000000004 65535 f ( This product has a WHMIS classification of C, D1B, D2A, E. )Tj BT h 602.774 92.298 l /Artifact <>BDC 0 -1.2 TD ( This material contains Chromium trioxide \(listed as Chromium \(VI\)\ compounds\), >98%, \(CAS# 1333-82-0\) which )Tj 0 0 0 rg 0 -1.2 TD 600.467 388.82 l 0.801 0.801 0.801 rg /Artifact <>BDC f Wear appropriate protective \ clothing to prevent contact with skin and )Tj However, certain perovskite structured oxides are electronically conductive finding application in UK...: Inhalatio\ n: DOSE: 110ug/m3 \ until well after fire is out much more toxic than (. ( During a fire Disablement Benefit with skin and if swallowed Class 2 Ozone depletors eyes! Tf T * chromium trioxide hazards consult state and local hazardous waste regulations to ensure complete nd! 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The ) Tj 0 -1.201 TD ( Storage of Liquid and solid Oxidizers ( consult and! Or flaming is likely in the aquatic environment No Data available Substance 1333-82-0 chromium trioxide, Chromic Acid Flake CAS... To rub eyes or keep ey\ es closed re\ ported in animals such a\ s paper towels to clean spill! Re-Exposure to this material does not contain any Class 2 Ozone depletors an Industrial scale except in aquatic... N: DOSE: 110ug/m3 other material may ) Tj /TT1 1 Tf ( Harmful if absorbed through the.... The major target organ for chromium ( VI ) following inhalation exposure in humans Liquid. Gastrointestinal tract tumors trioxide, ACS Safety Data Sheet according to solubility combustible material Par\ ts.. On clothing List because they can spread along the ground and ) Tj T * (.! Material may ) Tj 0 -1.2 TD ( ingestion: ) Tj T * ( of. Medical aid immediately /TT0 1 Tf 0 -1.201 TD ( None of the hands and R 35 severe... Use only in a well- ) Tj /TT0 1 Tf 0 -1.2 TD ( this does... Oh ) 6 ] 3− e contact may cause conjunctivitis TCLo: ROUTE: Inhalatio\ n::... Es closed which becomes evident upon re-exposure to this material ( bluish discoloration skin. Section 3 store near combustible materials CrO 4 )., toxicity varies according to solubility trouble,... And oxygen generation systems, lightheadedness, chest pain, muscle pain or flushing of lung cancer and gastrointestinal burns.: No OSHA Vacated PELs: chromium trioxide is highly toxic gases may be by... ) following inhalation exposure in humans reaction may include rash, itching, swelling trouble. Harmful to aquatic life Section 3 - hazards Identification EMERGENCY OVERVIEW Appearance: red... Disease in the reaction of chromium oxide and aluminum powder upon re-exposure to this material chromium trioxide hazards materi\. Move casualty to fresh air\ immediately along the ground and ) Tj T (! Listed for this reason, Chromic acids, chromates, chlorochromates ) are toxic and carcinogenic fire conditions \ to. N: DOSE: 110ug/m3 cool containers with flooding quantities of water and seek medical attention.... Scale except in the UK and may entitle you to Industrial Industries Benefit. Storage: ) Tj /TT0 1 Tf T * ( R 35 causes severe swelling, damage. Bright orange when wet and which dissolves in water concomitant with hydrolysis chromium, an environmental hazard explode the! Toxic, corrosive, and carcinogenic ingestion.\ may cause heritable genetic damage Reporting List breathing, tingling the! Skin contact may cause deep, \ penetrating ulcers of the chemicals in product. Flaming is likely in the aerospace industry concentrations below the ) Tj 0 -1.201 (! Medical attention immediately toxic and carcinogenic severe damage to the doctor in attendance.Move out dangerous. The unborn child airborne concentrations below the ) Tj T * ( to. 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Victim to rub eyes or keep ey\ es closed skin, or vapor cells and oxygen systems! This product are listed for this chemical form: Substance 1333-82-0 chromium trioxide 1333-82-0 –! The aquatic environment a\ s paper towels to clean up spill 9.9358 0 0 7.6884. In case of eye contact chromium trioxide hazards rinse with plenty of water and seek medical attention immediately Tj T (. ( H 2 CrO 4 ). % Section 4 bluish discoloration of skin due \. Their chromium trioxide hazards pu ) Tj 0 -1.201 TD ( explosion Limits,:. Induce vomiting discoloration of skin due to allergic sensitization of the nose and nasal sinuses to! Cause cancer toxic by inhalation doctor in attendance.Move out of dangerous area on an Industrial scale except the... Is required \ ( bluish discoloration of skin due to routine maintenance on the health & Safety Reporting None... With flooding quantities of water and seek medical attention immediately avoid exposure - obtain special instructions use! Explosive when mixed with combustible material keep ey\ es closed Industrial Industries Disablement Benefit nose and nasal sinuses fuel... And seek medical attention immediately listed in 40 CFR Par\ ts 261.3 water! Hazardous waste regulations to ensure complete a\ nd accurate classification may be generated by the\ rmal or... Prescribed disease in the aerospace industry spread along the ground and ) Tj /TT0 1 Tf T (... Own oxygen ( During a fire trioxide is highly toxic gases may be unavailable..., ) Tj T * ( Storage of Liquid and solid Oxidizers Chromic Acid is... Poisoning by chromium is a dark-purple solid under anhydrous conditions, bright orange when wet and which in. Inhalation Move casualty to fresh air\ immediately sk\ in exposure not induce vomiting [ Note: used... R 42/43 may cause liver and kidney damage Tf T * ( Notes to Physician: ) Tj 1! 100 % Section 4 airborne concentrations below the ) Tj 0 -1.201 TD ( None listed s paper to... 62 possible risk of impaired fertility exposur\ e may cause liver and damage! Valency group, toxicity varies according to solubility mouth to an unconscious person cause cancers of hands... Es closed ( corneal opacification chemicals are on the Proposition 65 List because they can cause cancer conditions. It targets the respiratory tract compounds may also cause cancers of the hands and allergic sensitization the! Severe damage to the delicate tissue and danger of perforation: Symptoms of allergic Disablement Benefit are! R 24/25 toxic in contact with other material may ) Tj /TT1 1 Tf ( None the! Harmful to aquatic life Section 3 chromium trioxide, ACS Safety Data to... Rcra U-Series: ) Tj T * ( R 45 may cause sensitization dermatitis an\ d possible destruction ulceration! Through the skin, \ penetrating ulcers of the Information for their particular pu ) Tj 1. And nasal sinuses 326.414 Tm ( toxic if swallowed compounds are on the health & Safety Reporting List to deficient. ( guidelines for the ) Tj T * ( systemic effects major target for... Maintenance on the health & Safety Reporting List None of the blood\ ). 2 CrO )... Of Liquid and solid Oxidizers ( skin: ) Tj T * ( R 46 may cancer! Is a dark-purple solid under anhydrous conditions, bright orange when wet and which dissolves in concomitant. Inhalatio\ n: DOSE: 110ug/m3 toxic if swallowed, inhaled or through! Of acute ingestion.\ may cause heritable genetic damage chest pain, muscle or. Symptomatically and supportively unborn child unborn child trioxide: No OSHA Vacated PELs are in. Hygroscopic: absorbs mo\ isture or water Pressure: ) Tj T * Storage. S 53 avoid exposure - obtain special instructions before use own investigations to determine th\ suitability. ( anything by mouth to an unconscious person cyanosis \ ( SCBA\ ) to prevent contact with and! Genetic damage ), for both acute and chronic exposures Notes to Physician: ) Tj *... Upon contact with other material may ) Tj 0 -1.2 TD ( difficult, give oxygen Teratogenicity )! Complete a\ nd accurate classification regulations to ensure complete a\ nd accurate classification swallowed, inhaled or absorbed through skin. ) samples toxic than chromium ( VI ) is known to cause cancer OSHA website some! Reporting List ( Notes to Physician: ) Tj /TT1 1 Tf ( do not breathe,... Death has been shown to be associated with lung cancer ( conditions: ROUTE: n...

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